
By Stig Sunner
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REFERENCES 1. 2. 3. 4. 5. 6. 7. 8. W h i t e , W . P . The Modern Calorimeter. The Chemical Catalog Company: New York. 1928. G i n n i n g s , D . C , W e s t , E . D . Experimental Thermodynamics, Vol. 1. M c C u l l o u g h , J . P . , S c o t t , D . W . , e d i t o r s . B u t t e r w o r t h s : London. 1968. 4. , Tappe, E . M o n a t s b e r . D e u t s c h . A k a d . W i s s . ( B e r l i n ) 1 9 6 7 , 9, 9 0 1 . , Tappe, E . M o n a t s b e r . D e u t s c h . A k a d . W i s s . ( B e r 1 i n ) 1968, 10, 88 and 1 0 2 .
Radiation. 7 a n d f is a f a c t o r d e p e n d i n g on t h e e m i s s i v i t i e s , nW m"" K~ a n d e ^ , o f t h e t w o s u r f a c e s o v e r l o o k i n g e a c h o t h e r . 01 i n w h i c h c a s e t h e r a d i a t i v e p o w e r i s r e d u c e d t o o n e p e r cent of its b l a c k - b o d y v a l u e . 053. 1 2 h a s a s u r f a c e o f 0 . 2 6 m , i t s e n e r g y e q u i v a l e n t i s 2 9 k J K"~ . R a d i a t i o n i s a t 2 9 8 K r e s p o n s i b l e for ca. 082 J SK~ .
T h i s m a t t e r (air, l e a d s , s u p p o r t s , e t c . ) w i l l be c o n s i d e r e d u n c h a n g e d d u r i n g an e x p e r i m e n t . T h e system has then a characteristic constant governing the c o n d u c t i v e p a r t of the h e a t e x c h a n g e , d e f i n e d from the s t e a d y state r e l a t i o n , a s s u m i n g e a c h m a t e r i a l to be h o m o g e n e o u s P , = cd - E 1 X(i)A(i)(3T/3x) e15 1 1 1 H e r e , X ( i ) is t h e h e a t c o n d u c t i v i t y in J cm"" s*"" K"~ o f m a t e r i a l i, A ( i ) is t h e a r e a c o v e r e d b y t h a t m a t e r i a l , 3 T / 3 x i s t h e t e m p e r a t u r e g r a d i e n t a l o n g the s p a c e c o o r d i n a t e x, p e r p e n d i c u l a r t o t h e p a r a l l e l s u r f a c e s .